Journal of the American Chemical Society
Atoms and Bonds as Synergisms of Interacting Electrons and Nuclei. The Origin of Chemical Bonds in Polyatomic Molecules.
Daniel Del Angel Cruz, Mark S Gordon, Klaus Ruedenberg
Published: 202510.1021/jacs.5c07438
Abstract
In quantum mechanical elucidations, the molecular energy of formation from the free atoms is an aggregate of cooperativities (synergisms) of orbital interactions. Frequently, such synergisms are deduced from model wave functions, which are assumed in…
Preview only. Read the full abstract at the source