Organic letters
Deoxygenative Asymmetric Cyanation with P(OEt)3 Employing Cooperative Photoredox Catalysis and Copper Catalysis.
Hongzhou Yu, Xiang Yu, Mengru Niu, Xin Wen, Yuqing Shao, Fang Fang, Guoyu Zhang
Published: 202610.1021/acs.orglett.5c05116
Abstract
The merger of photoredox catalysis with asymmetric copper catalysis has been successfully achieved, enabling the conversion of simply preactivated achiral alcohols into enantiomerically enriched alkyl nitriles via deoxygenation with organophosphorus(…
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