Employing Arylboronic Acids in Nickel-Catalyzed Enantioselective Suzuki-Type Cross-Couplings: Access to Chiral α-Aryl Phosphonates and α-Aryl Esters.

Herein, we report a nickel-catalyzed asymmetric Suzuki-Miyaura cross-coupling of racemic α-halo phosphonates and α-halo esters with various readily available arylboronic acids. This reaction provides facile access to a broad range of chiral α-aryl ph…

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