Organic letters
Photochemical Thioester Transfer to Alkynes via Selective Hydrothiocarbonylation.
Amit Pal, Prakash Maity, Fathima Niloofar, Basudev Sahoo
Published: 202610.1021/acs.orglett.5c05005
Abstract
We report the first hydrothiocarbonylation of (un)activated alkynes using bench-stable 1,4-DHP thioester surrogates under photochemical conditions, enabling a general route to (E)-α,β-unsaturated thioesters with excellent regio- and stereoselectivity…
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