Organic letters
Decaphyrin Conformers Stabilized by Pseudo-Rigid Dipyrrolylbenzothiadiazole Blocks: Synthesis, Structures and Interconversion.
Zhen Yang, Glib Baryshnikov, Shijun Li, Bin Zhu, Chengjie Li, Hans Ågren, Hailong Wang, Jianxin Song, Jianzhuang Jiang, Qizhao Li, Yongshu Xie
Published: 202610.1021/acs.orglett.5c04727
Abstract
Two conformers of a dipyrrolylbenzothiadiazole (DP-BTD) embedded decaphyrin(1.1.1.0.0.1.1.1.0.0) have been synthesized and separated, exhibiting crescent-shaped and figure-eight conformations, respectively. Incorporation of the hydrogen bonding-reinf…
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