Organic letters
Synthesis of Keto Hexafluoro Alkyl Sulfonyl Amides Via Radical Ring-Opening Polymerization of Aryl-Substituted Vinyl Cyclohexafluoropropane-1,3-bis(sulfonyl)amides Followed by Hydrolysis.
Takuji Kawamoto, Moeri Terauchi, Tetsushi Yamasaki, Takahiro Kawabata, Kenshin Muramatsu, Akio Kamimura
Published: 202510.1021/acs.orglett.5c04505
Abstract
The radical reaction of aryl-substituted vinyl cyclohexafluoropropane-1,3-bis(sulfonyl)amides (c-HFSI) followed by hydrolysis affords novel fluoroalkyl compounds. The key process in this reaction is the radical addition of c-HFSI to vinyl triflate, w…
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