Organic letters
Asymmetric Allylation/Retro-Claisen Cascade Reaction of 1,3-Diketones and 1-Hydroxyallylphenols/Aniline Catalyzed by an Iridium Complex.
Xiayu Zhang, Lixing Tan, Jiaxing Dong, Yungui Peng
Published: 202510.1021/acs.orglett.5c04493
Abstract
An asymmetric allylation/retro-Claisen cascade reaction of 1-hydroxyallylphenols/aniline with 1,3-diarylketones has been developed, and a series of chiral γ,δ-unsaturated 1,3-diaryl ketones could be produced in good to excellent yields (up to 87%) wi…
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