Organic letters
The Ylide Dance: Base-Induced Furan Synthesis via Formal [3+2] Annulation of Phenacyl- and Alkenyl Sulfonium Salts.
Danil A Myasnikov, Anastasia Y Khodus, Elena Y Mendogralo, Beauty K Chabuka, Igor V Alabugin, Igor V Trushkov, Maxim G Uchuskin
Published: 202510.1021/acs.orglett.5c04395
Abstract
A methodology for the synthesis of substituted furans via an "ylide dance" sequence has been developed. The reaction involves phenacyl sulfonium salts and alkenyl- or propargyl sulfonium salts under basic conditions. The key feature is a stepwise evo…
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