Organic letters
Halogen Atom Transfer (XAT)-Enabled Transition-Metal-Free Radical Annulation for the Construction of Phenanthrene-Derived Polycyclic Aromatic Hydrocarbons (PAHs).
Chen Zhou, Pei-Shang Li, Xue-Qing Wang, Yu-Ling Gu, Jia-Cheng Miao, Yi-Bin Wang, Sen Yang, Ming Chen, Yi-Yi Chen
Published: 202510.1021/acs.orglett.5c04255
Abstract
A transition-metal-free radical annulation strategy enabled by halogen atom transfer (XAT) has been developed for the direct construction of phenanthrene-derived polycyclic aromatic hydrocarbons (PAHs) from 2-iodobiaryls and terminal alkynes. This vi…
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