Organic letters
Merging Aldehydic C-H Activation with Strain Release C-C Bond Cleavage of Bicyclo[1.1.0]butanes under Rh(III) Catalysis.
Tanmay Barman, Om Prakash Dash, Jatin Patra, Chandra M R Volla
Published: 202510.1021/acs.orglett.5c04093
Abstract
Herein, we report a Rh(III)-catalyzed aldehydic C-H activation followed by strain release C-C cleavage of bicyclobutanes (BCBs) to access α-methylene-1,5-dicarbonyl motifs under mild conditions with excellent yields employing equimolar amounts of bot…
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