Enzymatic Enantioselective Protonation Regulated by an Artificial Enzyme Harboring an In Situ-Biosynthesized S-(3-Aminophenyl)-cysteine.

Significant progress has been made in the design of artificial enzymes using noncanonical amino acids; however, the field still faces considerable challenges. In this study, we present a novel approach for the design of an artificial enzyme capable o…

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