Organic letters
A Tsuji-Trost Reaction Using Free Carbenes as Nucleophiles: Palladium-Catalyzed Photoinduced Coupling of Acylsilanes with Allylic Alcohol Derivatives.
Ryosuke Masuda, Kento Ishida, Yuta Fujikura, Kanato Takahashi, Yuki Tanigawa, Yujiro Kato, Hiroyuki Kusama
Published: 202510.1021/acs.orglett.5c03678
Abstract
A palladium-catalyzed and photoinduced coupling reaction between acylsilanes and allylic alcohol derivatives based on the reactions of nucleophilic siloxycarbenes, generated via the light-induced isomerization of the corresponding aroyl-, heteroaroyl…
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