The journal of physical chemistry. A
Observation of the Ba(0) Complex BaNi(CO)3- Featuring the Shortest Bond between Barium and Transition Metal.
Zongchang Han, Luyan Meng, Jiaye Jin, Han-Shi Hu, Jun Li, Chaoxian Chi, Mingfei Zhou
Published: 202510.1021/acs.jpca.5c06108
Abstract
The heteronuclear barium-nickel anion complex BaNi(CO)3- is prepared in the gas phase and studied by mass-selected infrared photodissociation spectroscopy as well as quantum chemistry calculations. The complex exhibits a 2A1 ground electronic state a…
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