The Journal of organic chemistry
Enantioselective Construction of Inherently Chiral Heteracalixarenes via an NHC-Catalyzed (Dynamic) Kinetic Resolution.
Jiale Zhang, Yuxuan Feng, Qifan Du, Chang Guo, Jing Qi, Jincan Zhao, Xiao-Yong Duan
Published: 202510.1021/acs.joc.5c02463
Abstract
We have disclosed an NHC-catalyzed (dynamic) kinetic resolution approach for the facile construction of inherently chiral calix[4](hetero)arenes. Commercially available (hetero)aromatic, alkyl aldehydes, enals, and α-bromoenals were used as acylation…
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