The Journal of organic chemistry
4,7-Functionalization of Tetradentate Phenanthroline Ligands via Nucleophilic Substitution of Fluorine.
Roman V Zonov, Nane A Avagyan, Pavel S Lemport, Victor N Khrustalev, Vitaly A Roznyatovsky, Yuri A Ustynyuk, Valentine G Nenajdenko
Published: 202610.1021/acs.joc.5c02395
Abstract
An effective pathway for the functionalization of 1,10-phenanthroline-2,9-dicarboxamides (DAPhen) to positions 4 and 7 of the heterocyclic backbone by nucleophilic aromatic substitution was developed. The developed approach makes it possible to intro…
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