The Journal of organic chemistry
MgI2-Mediated Solvent-Controlled Divergent Ring-Opening Cyclization/Addition of Spirocyclopropyl Indanediones.
Ting Yang, Ze-Gang Ma, Wen-Hui Zhang, Zhen-Nan Shan, Ying Zhou, Li-Yan Zhang, Chuan-Wen Lei
Published: 202510.1021/acs.joc.5c02354
Abstract
MgI2-mediated formal (3 + 2) cycloaddition (ring-opening cyclization) and ring-opening iodination-Michael addition of spirocyclopropyl indanediones and nitroalkenes have been developed respectively in tetrahydrofuran and toluene, which constitutes an…
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