The Journal of organic chemistry
Photomediated Solvent-Switched Direct C-H Arylation vs Oxyalkylation of Azauracils Using Unactivated Aryl Iodides.
Raman Kumar, Manpreet Kaur, Anuj Sharma
Published: 202610.1021/acs.joc.5c02086
Abstract
Herein, we report a unified, photoinduced, solvent-controlled strategy for two distinct C-H functionalizations of azauracils: arylation in DMSO and oxyalkylation in THF via direct homolytic cleavage of the C-I bond of photoexcited aryl iodides. Mecha…
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