The Journal of organic chemistry
C(2) and C(5) Nucleophilic Functionalization of 4H-Imidazole-3-oxide Exposed to Carboranyllithium.
Yuriy A Seleznev, Igor A Lavrinchenko, Timofey D Moseev, Mikhail V Varaksin, Anton N Tsmokaluk, Dmitrii G Mazhukin, Alexsei Y Tikhonov, Valery N Charushin, Oleg Chupakhin
Published: 202510.1021/acs.joc.5c01956
Abstract
The dual reactivity of 5-aryl-4H-imidazol-3-oxides with respect to carboranyllithium has been studied. In particular, in the presence of an oxidizing agent, the reaction of nucleophilic substitution of hydrogen by the mechanism of addition-oxidation…
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