The Journal of organic chemistry
Photoredox-Catalyzed Hydrofluoromethylthiolation of Unactivated Alkenes to Access Alkyl Di- and Trifluoromethyl Sulfides.
Xiao-Qing Feng, Li-Li Zeng, Shi-Han Xu, Liang Shen, Xian Feng, Rong-Hui Huang, Fen-Er Chen, Jian Han
Published: 202510.1021/acs.joc.5c01829
Abstract
Herein, a visible-light-induced photocatalytic hydrofluoromethylthiolation of unactivated alkenes for the efficient construction of aliphatic di- and trifluoromethyl sulfides (47 examples, up to 93% yield) is described. In contrast to previous method…
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