Inorganic chemistry
Effect of Fluorinated Alcohols on the Reactivity and Selectivity of the Oxoiron(V) Intermediates in C(sp3)-H Oxidations.
Alexandra M Zima, Oleg Y Lyakin, Anna A Bryliakova, Konstantin P Bryliakov, Evgenii P Talsi
Published: 202610.1021/acs.inorgchem.5c05812
Abstract
In recent years, β-fluorinated alcohols have been increasingly utilized as reaction solvents in a variety of direct hydroxylations of aliphatic C-H bonds, catalyzed by bioinspired Fe-, Mn-, Ni-, and Pd-based catalysts. However, direct experimental da…
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