Inorganic chemistry
The Nature of Nonclassical Chalcogeno-Carbonyl Ligands.
María L G Sansores-Paredes, Michelle P van Dongen, Celine Nieuwland, Pascal Vermeeren, F Matthias Bickelhaupt, Célia Fonseca Guerra
Published: 202610.1021/acs.inorgchem.5c05165
Abstract
Coordination of chalcogeno-carbonyl ligands CX (X = O, S, Se) to transition metals can induce either expansion (classical) or contraction (nonclassical) of the C-X bond. While nonclassical CO complexes have been extensively studied, the heavier analo…
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