Inorganic chemistry
Atomic-Level Integration of Heterometallic Cooperativity and Photonic Energy Harvesting in a Molecular Water Oxidation Catalyst.
Feng Fu, Jing Du, Qingqing Huang, Xu Zhang, Dafeng Yan, Xu Peng, Xianliang Fu, Yuanmeng Zhao, Hai-Bing Xu
Published: 202610.1021/acs.inorgchem.5c05089
Abstract
Inspired by the heterometallic cooperativity of metalloenzymes, we report a trinuclear molecular catalyst, [NiL]2-Ce-O-Fe, engineered through adaptive coordination of a π-extended salen-type ligand. This design integrates three synergistic functions:…
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