Inorganic chemistry
Reduction of Nitrite to NO on a Molybdenum-Thiolate Platform and Protonation of the Anionic Nitrosyl Complex.
Jianglan Liu, Jia-Yi Chen, Zhiqiang Peng, Lan Liu, Rong-Zhen Liao, Wenguang Wang
Published: 202610.1021/acs.inorgchem.5c04930
Abstract
We report nitrite-to-NO reduction using Mo(P^S^S)2 (1, where P^S^S = PhP(o-C6H4S-)2), and explore the protonation of the resulting anionic Mo(IV)-NO complex (2) as a potential for further transformations. In the absence of benzenethiol as an external…
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