Inorganic chemistry
Why Cd Outcompetes Zn at Sulfur: Transferable Orbital Rules from Hydration to Thiolate Binding.
Akef T Afaneh, Ahmad Al-Rahamneh, Ali Marashdeh, Wissam Helal
Published: 202610.1021/acs.inorgchem.5c04922
Abstract
Cadmium's persistent preference over zinc at sulfur affects biology, sensing, and separations, yet a general predictive rationale from aqueous speciation to thiolate binding has been lacking. We integrate continuum-solvation thermodynamics with Natur…
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