Inorganic chemistry
Synthesis, Characterization, and Reactivity Study of a Chromium(VI) Neopentylidene Complex.
Yiru Fan, Yanhua Yu, Qi Wang, Min Shao, Pengcheng Wu
Published: 202610.1021/acs.inorgchem.5c04920
Abstract
The bis(arylimido)chromium(VI) dineopentyl complex, (ArN)2Cr(CH2tBu)2 (Ar = 2,6-diisopropylphenyl), undergoes α-hydrogen abstraction to generate a coordinatively unsaturated neopentylidene intermediate, which can be trapped by a σ-donor ligand (tetra…
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