Inorganic chemistry
O2 Activation at a Low-Valent P-Center: Isolation of a Cyclic Alkyl(Amino) Carbene (cAAC)-Phosphonate-Supported Dicationic Cu(II)6 Cluster.
Asutosh Patra, Maria Francis, Kishor Shinde, Farsana Abdul Salam, Akshara Purushothaman, Sudipta Roy
Published: 202610.1021/acs.inorgchem.5c04888
Abstract
Herein, we explore the coordination behavior and O2-activation of molecular diphosphorus (P2) in the presence of CuX (X = Cl, Br), unraveling the phosphinidene nature of low-valent phosphorus atoms. Both mono- and dicuprated P2 complexes with general…
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