Inorganic chemistry
Non-IPR Chlorofullerenes Obtained from IPR C60 by Stone-Wales Rearrangements, #1809C60Cl10 and #1806C60Cl26.
Nadezhda B Tamm, Natalia S Lukonina, Vladislav P Shakhov, Konstantin A Lyssenko, Alexey A Goryunkov, Victor A Brotsman
Published: 202610.1021/acs.inorgchem.5c04808
Abstract
Chlorination of isolated pentagon rule (IPR)-fullerene C60 with a SbCl3/SbCl5 mixture at 320 °C and pure SbCl5 at 500 °C promotes Stone-Wales rearrangements leading to non-IPR chlorofullerenes #1809C60Cl10 (with ca. 15% yield) and #1806C60Cl26 as low…
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