Inorganic chemistry
Noninnocence Driven Superexchange Within a Ti2+/Ti4+ Mixed Valence Complex.
Colby Seth Bell, Elizabeth A Tonsel-White, Curtis E Moore, Evan Smith, Sudarshan Sharma, Julien A Panetier, Kensha Marie Clark
Published: 202610.1021/acs.inorgchem.5c04747
Abstract
An example of a molecular Ti2+/Ti4+ complex is reported, whereby the metal centers are bridged by the redox-active tetrakis(imino)pyracene ligand (TIP). Spectroscopic, electrochemical, electronic structure calculations, and magnetic analyses were use…
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