Inorganic chemistry
A Flexidentate Bipyridine-Aza-Crown Ether Ligand Enables Cation-Tunable Nickel Redox Properties.
Elsa Z Huebsch, Sebastian Acosta-Calle, Grant A Richter, Jenna E Halenda, Zoe E Stuart, Chun-Hsing Chen, Alexander J M Miller
Published: 202610.1021/acs.inorgchem.5c04638
Abstract
A strategy for modulating the coordination mode and redox properties of nickel complexes is introduced, using a 2,2'-bipyridine derivative featuring a flexidentate and cation-responsive aza-crown ether. The bipyridine-aza-crown ether ligand can rever…
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