Inorganic chemistry
Electronic Structure Tuning of Lanthanidocene Photocatalysts for C-F Bond Cleavage.
Elias Tanuhadi, Nicholas J Katzer, Polly L Arnold
Published: 202510.1021/acs.inorgchem.5c04580
Abstract
A set of nine new robust, tunable cerium complexes supported by an ansa-bis(cyclopentadienyl) ligand, [Me2Si(η5-CpR)2]CeX (anCpR)CeX, are excellent homogeneous visible-light photocatalysts for the monodefluoroalkylation of trifluorotoluene with Mg(CH…
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