Inorganic chemistry
Heteroligated Hafnium Complexes with Enhanced Activity and Thermal Stability toward Olefin (Co)polymerization.
Yongxin Liu, Faqiang Niu, Shaofeng Liu, Zhibo Li
Published: 202610.1021/acs.inorgchem.5c04568
Abstract
Three heteroligated Hf metal complexes, [C5H4N-CH(Me)-N-2,6-R1-C6H3][C6H5-N-C6H4-S-R2]HfMe2 (for Hf1/3, R1 = iPr and R2 = Me; for Hf2/3, R1 = Me and R2 = Me; for Hf2/4, R1 = Me and R2 = Ph), have been prepared from orthogonal reactions between pyridy…
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