Inorganic chemistry
Using a Radical Straitjacket to Enforce an Ultrashort Dy-Dy Distance and Thus Enhance Dipolar Interactions in a DyIII2 Dimer.
Anthony B Carter, Jonas Braun, Tilmann Bodenstein, Rouven F Pfleger, Michael Schulze, Thomas Kriese, Sebastian F M Habermann, Dan Liu, Abdullah A Al-Kahtani, Eufemio Moreno-Pineda, Christopher E Anson, Wolfgang Wernsdorfer, Liviu F Chibotaru, Karin Fink, Annie K Powell
Published: 202510.1021/acs.inorgchem.5c04406
Abstract
We present three air-stable radical-containing compounds, [MIII2(phsq)4(NO3)2(MeOH)2]·2MeOH (M = Dy (1), Y (2), Gd (3); Hphsq = 9,10-phenanthrenesemiquinone), in which strong intramolecular inter-radical interactions force two lanthanide ions into cl…
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