Inorganic chemistry
Hybrid Salt of Mo6 Cluster and Keggin-Type Silicotungstate: Enhancing the Efficiency of Photocatalytic Hydrogen Evolution via S-Scheme Heterojunction Formation.
Danil A Polskikh, Anton A Petunin, Timur R Fazliev, Dmitry S Selishchev, Michael A Shestopalov, Taisiya S Sukhikh, Igor P Asanov, Anton A Ivanov, Yuri A Vorotnikov
Published: 202610.1021/acs.inorgchem.5c04371
Abstract
In this study, we report the synthesis and characterization of a novel hybrid compound, [Mo6I8(H2O)6][α-SiW12O40]·12H2O (denoted as [MoI][SiW]), formed by the electrostatic interactions between a cationic molybdenum aqua complex and an anionic Keggin…
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