Structure, Bonding, and Stabilization Mechanism of High-Spin Cobalt- and Nickel-Based Metalized Borylene Complexes [(OC)BM(CO)n][M2(CO)6]+ (M = Ni, Co; n = 2, 3).

Borylenes (:BR) have garnered extensive interest in small-molecule activation due to their unique amphoteric reactivity, and thus, stabilizing these species remains of paramount importance for realizing their practical applications. Recently, metaliz…

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