Inorganic chemistry
Following CO and H Insertion into Ru-C Bonds with X-ray Photoelectron and Absorption Spectroscopies.
Irene Barba-Nieto, Jorge Moncada, Andressa V Müller, Ning Rui, Charles J Titus, Cherno Jaye, Gerald J Meyer, Javier J Concepcion, José A Rodriguez
Published: 202510.1021/acs.inorgchem.5c03822
Abstract
Insertion reactions play a central role in the catalytic synthesis of ethanol and higher alcohols. X-ray photoelectron and absorption spectroscopies have been used to follow migratory CO insertion and C─C coupling in a cis-[Ru(2,2'-bipyridine)2(CO)(C…
Preview only. Read the full abstract at the source