Inorganic chemistry
Phosphine and Arsine MOFs with Stabilized Diosmium(I) Carbonyl Sawhorse Pillars.
Samuel K Emslie, Benjamin Patterson, Ashley K Archambeau, Adrienne H Schumacher, R Eric Sikma, Connor J O'Dea, Serhii Vasylevskyi, Zachariah A Page, Cynthia B Powell, Graeme Henkelman, Gregory L Powell, Simon M Humphrey
Published: 202510.1021/acs.inorgchem.5c03820
Abstract
A new metal-organic framework (MOF) with low-valent, σ-bonded OsI-OsI pillars has been prepared using [Os2(ER3)2(μ2-O2CH)2(CO)4] sawhorse complexes (ER3 = {E(C6H4CO2)}3-; E = P or As). This is the first example of the inclusion of OsI into a MOF and…
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