Inorganic chemistry
Bulky (Imino)phosphide and Mixed Bis-dimethyl-siloxane /(Imino)phosphide-supported Redox-Active Cu5 and Cu6 Nanoclusters: Luminescence and Photocatalytic Studies.
Asutosh Patra, Kishor Shinde, Sourav Mandal, Ashwath Kudlu, Wei-Dan Si, Maria Francis, Aloke Das, Di Sun, Sudipta Roy
Published: 202510.1021/acs.inorgchem.5c03056
Abstract
Herein, we depict isolation of neutral air-stable atomically precise Cu5 [((R2-cAI)P(Dipp))3Cu5Cl2] (cAI = cyclic alkyl(imino); Dipp = 2,6-diisopropylphenyl; R2 = Cy (2a) and Et2 (2b)) and Cu6 [((Et2-cAI)P(Dipp))2Cu6(OSiMe2OSiMe2O)2] (3) nanoclusters…
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