Inorganic chemistry
Water-Soluble Rhenium Nitride Complexes Supported by Multidentate Phosphinite Ligands Provide Insights into Aqueous Ammonium Synthesis Using Samarium Diiodide.
Noah D McMillion, Mehrnaz Aliahmadi, Quinton J Bruch, Chun-Hsing Chen, Alexander S Hegg, Patrick L Holland, Alexander J M Miller
Published: 202510.1021/acs.inorgchem.5c03010
Abstract
Metal nitride complexes are key intermediates in ammonia synthesis. Although water would be an ideal source of protons, the synthesis of ammonia from well-defined nitride complexes in water is underexplored. The aqueous reactivity of rhenium nitride…
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