Inorganic chemistry
Unveiling the Effect of Symmetry-Breaking Charge Transfer on Intersystem Crossing in Group 14 TADF Emitters.
Anitha S Gowda, Marisa N Tordella, Glenn P A Yap, Jeffrey L Petersen, Carsten Milsmann
Published: 202510.1021/acs.inorgchem.5c02929
Abstract
Three organotetrel compounds (MePDPPh)EMe2 (E = Si, Ge, Sn) have been synthesized by the reaction of 2,6-bis(5-methyl-3-phenyl-1H-pyrrol-2-yl)pyridine (H2MePDPPh) with EMe2Cl2. All three molecules show photoluminescence (ΦPL = 0.66-0.75) through a co…
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