Inorganic chemistry
Ruthenium(0)-Mediated Successive N-H and S-H/C-H Bond Activation in Selected Imine Ligands: Elucidation of the Activation Mechanism and Application in Borrowing Hydrogen Catalysis.
Anushri Chandra, Satyaki Kundu, Papu Dhibar, Anannya Saha, Piyali Paul, Samaresh Bhattacharya
Published: 202610.1021/acs.inorgchem.5c02501
Abstract
The reported study demonstrates the remarkable ability of the ruthenium(0) center in [Ru(CO)3(PPh3)2] to bring about σ-bond activation in organic molecules. This has been exemplified through reactions of [Ru(CO)3(PPh3)2] with two types of imine ligan…
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