A multi-pass differential photoacoustic spectrometer at 1064 nm for ambient aerosol absorption.

Accurate atmospheric aerosol absorption measurements are critical for advancing our understanding of global climate effects and reginal meteorological processes. In this paper, a multi-pass differential photoacoustic spectrometer (MP-DPAS) worked at 1064 nm, was developed for the in-situ measurement of atmospheric aerosol absorption coefficients (Abs). By employing the multi-pass configuration, 22 reflections of the incident laser were achieved, thereby the photoacoustic signal was enhanced by a factor of ten. Meanwhile, the differential configuration not only suppress background noise but also amplifies the signal by a factor of two. Consequently, the MP-DPAS achieved a minimum detection limit of 0.05 Mm-1 within an integration time of 110 s and a precision of 1.4 Mm-1. The accuracy of the MP-DPAS was validated by comparing the measured Abs with the calculated Abs of Mie scattering theory and the variation of particle size distribution measured by SMPS (Scanning Mobility Particle Sizer).