Journal of inorganic biochemistry
Effects of ligand topology and iron coordination number on the electronic structure of FeIII-μ-oxo-CrIII complexes supported by tetramethylcyclam.
Ruixi Fan, Jin Xiong, Ang Zhou, Wei-Min Ching, Patrick M Crossland, Barbara Lavina, Michael Y Hu, Jiyong Zhao, Esen E Alp, Lawrence Que, Yisong Guo
Published: 202510.1016/j.jinorgbio.2025.113054
Abstract
57Fe Mössbauer, electron paramagnetic resonance, and 57Fe nuclear resonance vibrational spectroscopies are applied to characterize three different FeIII-O-CrIII complexes derived from the tetramethylcyclam (TMC, 1,4,8,11-tetramethyl-1,4,8,11-tetraaza…
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