Synthesis of Bifunctional Ag@Porphyrin Nanostructures for Single-Particle SERS Operando Tracking of Ferryl Intermediates in Iron-Porphyrin Complexes.

Metalloporphyrins have been extensively employed as model systems for mimicking heme enzymes and single-site catalysts. Understanding their catalytic mechanism at the molecular level, especially through in situ/operando characterization is of signifi…

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