Chemistry, an Asian journal
Reductive Generation of Anionic C1 Carbenoid Species Attached to Organosulfur Functional Groups.
Kazuhiro Okamoto, Shuto Wada, Kensuke Muta, Yuta Tsuchihashi, Aiichiro Nagaki
Published: 202610.1002/asia.70525
Abstract
The generation of heteroatom-substituted C1 carbenoids is highly challenging due to their extreme instability and electronic perturbations. We report the reductive lithiation of organosulfur chloromethyl precursors using lithium naphthalenide (LiNp)…
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