Angewandte Chemie (International ed. in English)
Hydroxyl Radicals Unlock Strong C(sp3)─Si Bonds: Photocatalytic Alkylation and Silacycle Engineering.
Bo Li, Xingyi He, Yizhi Zhang, Kang Li, Yingmo Zhang, Shanshan Liu, Yu-Cheng Gu, Xiao Shen
Published: 202610.1002/anie.202523587
Abstract
Organosilicon reagents play a significant role in the preparation of molecules essential to synthetic chemistry, materials science, and medicinal chemistry. However, selectively transforming strong C(sp3)─Si bonds in unactivated organosilicon reagent…
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