Angewandte Chemie (International ed. in English)
Bypassing β-Hydride Elimination: Excited-State Pd-Catalyzed C(sp3)-C(sp2) Coupling at Room Temperature.
Kuntal Pal, Rajesh Kancherla, Sayan Dutta, Serik Zhumagazy, Bholanath Maity, Luigi Cavallo, Magnus Rueping
Published: 202610.1002/anie.202522979
Abstract
Catalytic modification of C-H bonds using palladium is highly appealing, but transformations involving alkyl-Pd(II) intermediates with β-hydrogens are challenging due to the propensity for β-hydride elimination. To address this, selective arylation o…
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