Angewandte Chemie (International ed. in English)
Leveraging 3d-4f Coordination: Molecular Quantum Spring-Magnet Behavior in Axial Ni2Ln Complexes.
Zhaoyang Jing, Eufemio Moreno-Pineda, Sagar Paul, Appu Sunil, Olaf Fuhr, Yaorong Chen, Wolfgang Wernsdorfer, Mario Ruben
Published: 202610.1002/anie.202522076
Abstract
We report heterotrimetallic 3d-4f complexes, mimicking classical exchange spring magnets at the molecular scale. The complexes feature a linear Ni···Ln···Ni core, where the lanthanide ion is sandwiched between two Ni2+ centers coordinated by N3O3 lig…
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