Angewandte Chemie (International ed. in English)
Inert Complexes Unlock Ligand-Accelerated Transition-Metal Catalysis on Proteins.
Zhen Wang, Fengrui Xiang, Xingyu Liao, Qingsong Wu, Jinbiao Jiao, Angzhi Bi, Siyang Liu, Dan Wang, Minyan Wang, Zijian Guo, Jie P Li
Published: 202610.1002/anie.202522057
Abstract
Reactions that excel in small-molecule settings typically require metal loadings far exceeding the number of protein reaction sites (often ≥10-fold) once transplanted into proteinaceous media-conditions that are not truly "catalytic." Here, we show t…
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