Angewandte Chemie (International ed. in English)
Terpenoid Synthesis via Convergent Radical Annulation.
Alex L Rerick, Griffin L Barnes, Fabian Schneider, Luis Oxenfart, Phil S Baran
Published: 202610.1002/anie.202521852
Abstract
The development of a convergent radical annulation strategy for the synthesis of complex terpenoids from sclareolide is disclosed. This approach employs a 1,3-diradical synthon to enable rapid C-ring annulation through inter- and intramolecular radic…
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