Angewandte Chemie (International ed. in English)
Achieving Charge-Transfer from the Boron-Vertices of o-Carborane: Dual-Emission with a Shift of 505 nm (2.1 eV).
Xiaoyang Xu, Xueyuan Zhao, Shuang Xu, Xinning Zhang, Qihao Wang, Lin Wu, Xin Li, Junqing Shi, Jiani Ma, Lei Ji, Wei Huang
Published: 202510.1002/anie.202521735
Abstract
The boron-vertices of o-carborane have long been considered to be inert in conjugation with π-substituents. Herein, we demonstrate that the boron vertices of o-carborane can be engineered to participate in intense charge-transfer (CT) transitions. Th…
Preview only. Read the full abstract at the source